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Daniel Sieh, Mandy Schlimm, Lars Andernach, Friedrich Angersbach, Stefan Nückel, Julia Schöffel, Nevena Šušnjar and Peter Burger Metal–Ligand Electron Transfer in 4d and 5d Group 9 Transition Metal Complexes with Pyridine, Diimine Ligands European Journal of Inorganic Chemistry 2012

Version of Record online: 5 JAN 2012 | DOI: 10.1002/ejic.201101072

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The syntheses, X-ray crystal structures, and spectroscopic data for rhodium and iridium pyridine, diimine (PDI) complexes (PDI)Rh,Ir–Ln0,1+ (n = 1–3) are reported for a large variety of ligands L and different coordination numbers (CN = 4–6). The extent of metal–ligand electron transfer in these diamagnetic complexes was evaluated by experimental and theoretical methods.

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