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Stephan Hohloch, Pierre Braunstein and Biprajit Sarkar Ruthenium Hydride Complexes with Zwitterionic Quinonoid Ligands – Isomer Separation, Structural Properties, Electrochemistry, and Catalysis European Journal of Inorganic Chemistry 2012

Version of Record online: 13 DEC 2011 | DOI: 10.1002/ejic.201101091

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Ruthenium hydride complexes derived from zwitterionic quinonoid ligands have been synthesized, and their isomers have been separated and structurally characterized. Cyclic voltammetry of the complexes showed the redox noninnocent nature of the quinonoid ligands. One of the complexes showed good activity as a catalyst for the transfer hydrogenation of acetophenone.

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