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Michael M. Bittner, Jacob S. Baus, Sergey V. Lindeman and Adam T. Fiedler Synthesis and Structural Characterization of Iron(II) Complexes with Tris(imidazolyl)phosphane Ligands: A Platform for Modeling the 3-Histidine Facial Triad of Nonheme Iron Dioxygenases European Journal of Inorganic Chemistry 2012

Version of Record online: 27 FEB 2012 | DOI: 10.1002/ejic.201101282

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A series of monoiron(II) complexes with tris(imidazolyl)phosphane ligands have been generated and characterized by using X-ray crystallography. These complexes model the resting and substrate-bound states of certain nonheme iron enzymes, such as β-diketone dioxygenase and salicylate 1,2-dioxygenase, which employ three facially coordinating histidine ligands in their active sites.

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