Luís M. P. Lima, Rita Delgado, Petr Hermann, Radek Ševčík, Přemysl Lubal, Henrique F. Carvalho, André F. Martins, Éva Tóth and Carlos F. G. C. Geraldes Tris(phosphonomethyl)cyclen Derivatives: Thermodynamic Stability, Kinetics, Solution Structure, and Relaxivity of Ln3+ Complexes European Journal of Inorganic Chemistry 2012
Version of Record online: 12 APR 2012 | DOI: 10.1002/ejic.201101335
The properties of lanthanide(III) complexes of cyclen derivatives containing three methylphosphonate pendant arms are reported. The stability constants were determined as well as the dissociation kinetics of the cerium(III) complexes. Structural properties were determined by solution NMR and luminescence measurements. A relaxometric study of the complex of H6do3p1ol with Gd3+ was also undertaken.
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