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Agata Białońska, Robert Bronisz, Joachim Kusz, Marek Weselski and Maciej Zubko How Nonequivalency of the Flexibility of the Ligand Bridges Leads to Anisotropy of Perturbation Transmission in a 3D Spin-Crossover Coordination Network European Journal of Inorganic Chemistry 2013

Article first published online: 19 OCT 2012 | DOI: 10.1002/ejic.201200645

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In the 3D network, {[Fe(qbtr)3](ClO4)2} [qbtr = 1,5-di(1,2,3-triazol-1-yl)pentane], temperature decrease involves symmetry breaking and superstructure formation followed by spin crossover. The sequence Ph1 (HS,HS) [RIGHTWARDS ARROW] Ph2 (HS,HS,HS) [RIGHTWARDS ARROW] Ph3 (HS,LS) is accompanied by conformational alterations of the bridging ligand, the flexibility of which determines the effectiveness of perturbation transmission.

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