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Konstanze Kiersch, Yuehui Li, Kathrin Junge, Normen Szesni, Richard Fischer, Fritz E. Kühn and Matthias Beller Catalytic Epoxidations with Pyridinebis(oxazoline)–Methyltrioxorhenium Complexes and Nitrogen-Containing Catalyst Systems European Journal of Inorganic Chemistry 2012

Version of Record online: 6 NOV 2012 | DOI: 10.1002/ejic.201200736

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The epoxidation of 1-octene using methyltrioxorhenium (MTO) in the presence of pyridinebis(oxazoline) and related ligands is reported. Although excellent chemoselectivity (>90 %) and good yields were obtained, low enantioselectivity was observed.

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