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Stephan Roeser, Somnath Maji, Jordi Benet-Buchholz, Josefina Pons and Antoni Llobet Synthesis, Characterization, Reactivity, and Linkage Isomerization of Ru(Cl)2(L)(DMSO)2 Complexes European Journal of Inorganic Chemistry 2013

Version of Record online: 21 NOV 2012 | DOI: 10.1002/ejic.201200809

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Isomeric [Ru(Cl)2(L)(DMSO)2] complexes [L = 5-phenyl-3-(2-pyridyl)-1H-pyrazole, DMSO = dimethyl sulfoxide] are reported together with their structures, spectroscopic properties, electrochemistry, and S-to-O linkage isomerization. Additionally, a photolytic reaction of both isomers in chloroform is reported, which results in the formation of a third complex, [Ru(Cl)3(L)­(DMSO)].

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