Dmitri V. Konarev, Leokadiya V. Zorina, Salavat S. Khasanov and Rimma N. Lyubovskaya The Formation of 3D Fullerene Packing in Molecular Complexes of C60 and C70 with Metal Diethyl Dithiophosphates: [M(dedtp)2]·[C60(70)]3 (M = NiII, CoII, and VIVO) European Journal of Inorganic Chemistry 2013
A series of molecular complexes [M(dedtp)2]·[C60(70)]3 (M = NiII, CoII, and VIVO; 1–4; dedtp=diethyl dithiophosphate) were obtained and structurally characterized. The fullerenes in the complexes pack in a three-dimensional manner. Both [NiII(dedtp)2] and [CoII(dedtp)2] have square-planar geometry around the metal centers, whereas vanadium atoms in [VIVO(dedtp)2] exhibit a square-pyramidal environment.
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