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Ines dos Santos Vieira, Christina Dietz, Fabian Mohr, Rainer Beckert and Sonja Herres-Pawlis Oxalic Amidines – Protonation Studies and Activity in Lactide Polymerisation European Journal of Inorganic Chemistry 2013

Article first published online: 13 NOV 2012 | DOI: 10.1002/ejic.201200838

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The synthesis of a chloridozinc complex with an oxalic amidine ligand and its application as a catalyst in the ring-opening poly­merisation of lactide is reported. The polymerisation is well-controlled with good agreement between the experimental and theoretical molecular weights. Proton affinity studies and complex formation studies highlight the donor properties of the oxalic amidine compound.

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