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François Varret, Kamel Boukheddaden, Guillaume Chastanet, Nicolas Paradis and Jean-François Létard When T(LIESST) Meets Thermal Hysteresis – a Theoretical Approach European Journal of Inorganic Chemistry 2013

Article first published online: 21 NOV 2012 | DOI: 10.1002/ejic.201200863

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Theoretical overlap of stable and metastable states: A comprehensive study of the overlap between the T(LIESST) and the thermal spin-crossover curves based on simulations (LIESST = light-induced excited spin state trapping) is presented. The consequences of the overlap on the shape and the completeness of the SCO behavior are discussed and the kinetic phase diagrams established.

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