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Tobias Kloubert, Christoph Müller, Sven Krieck, Tina Schlotthauer, Helmar Görls and Matthias Westerhausen 3-(2-Pyridyl)-5-(2-thienyl)pyrazole and Complexes of Its Anion with Lithium, Magnesium, Calcium, and Zinc Ions European Journal of Inorganic Chemistry 2012

Version of Record online: 22 OCT 2012 | DOI: 10.1002/ejic.201200876

Thumbnail image of graphical abstract

3-(2-Pyridyl)-5-(2-thienyl)pyrazolate anions act as bidentate ligands and form five-membered metallacycles. In addition, these anions can adopt bridging modes as shown in the lithium complex (C grey, Li green, N blue, O red, S yellow; H omitted) or can be deprotonated a second time at the 3-position of the thienyl ring.

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