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Maria G. Babashkina, Damir A. Safin, Monika Srebro, Piotr Kubisiak, Mariusz P. Mitoraj, Michael Bolte and Yann Garcia Crucial Influence of the Intramolecular Hydrogen Bond on the Coordination Mode of RC(S)NHP(S)(OiPr)2 in Homoleptic Complexes with NiII European Journal of Inorganic Chemistry 2013

Article first published online: 11 DEC 2012 | DOI: 10.1002/ejic.201200890

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Reaction of deprotonated RC(S)NHP(S)(OiPr)2 [R = EtNH (HLI), iPrNH (HLII), Et2N (HLIII), 2,5-Me2C6H3NH (HLIV), 4-Me2NC6H4NH (HLV)] with NiII leads to [NiLI–V2]. The metal atom is found to be in a square-planar trans-N2S2 ([NiLII,IV2]) or in a square-planar trans-S2S′2 ([NiLI,III2]) environment. Reaction of LV with NiII leads to [Ni(L-1,3-N,S)2] or [Ni(L-1,5-S,S′)2]·(CH3)2C=O crystals.

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