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Christian Müller, Leen E. E. Broeckx, Iris de Krom and Jarno J. M. Weemers Developments in the Coordination Chemistry of Phosphinines European Journal of Inorganic Chemistry 2013

Version of Record online: 7 NOV 2012 | DOI: 10.1002/ejic.201200912

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We highlight recent achievements in the design of donor-functionalized, chelating 2,4,6-triarylphosphinine derivatives by the pyrylium salt route and illustrate strategies to access new neutral and cationic phosphinine-based transition metal complexes containing metal centres in various oxidation states, such as M0, MI, MII and MIII. Comparisons with isostructural nitrogen analogues are made.

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