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Delina Barats-Damatov, Linda J. W. Shimon and Ronny Neumann Hexagonal Supramolecular Assemblies Based on a RuII(DMSO)3- or OsII(DMSO)3-Capped {HW9O33} Isopolyanion with Potassium Cations as Linkers European Journal of Inorganic Chemistry 2013

Article first published online: 18 SEP 2012 | DOI: 10.1002/ejic.201200953

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{HW9O33} isopolyanions were capped by MII(DMSO)3 moieties (where M = Ru, Os), which were, in turn, linked by potassium cations to give polymer chains that were somewhat different for the Ru and Os analogues. For Ru, the 3D structures showed channels defined by six polymer chains with a diameter of ca. 8 Å, while for Os, two types of channels of ca. 5.5 Å were formed defined by three polymer chains.

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