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Ludmila G. Lavrenova and Olga G. Shakirova Spin Crossover and Thermochromism of Iron(II) Coordination Compounds with 1,2,4-Triazoles and Tris(pyrazol-1-yl)methanes European Journal of Inorganic Chemistry 2013

Version of Record online: 21 DEC 2012 | DOI: 10.1002/ejic.201200980

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This review describes the coordination compounds of iron(II) with 1,2,4-triazoles or tris(pyrazolyl)methanes as ligands. The complexes exhibit a thermally induced 1A1[LEFT RIGHT ARROW]5T2 spin-crossover phenomenon that is accompanied by a pink [LEFT RIGHT ARROW] white color change. These complexes are of interest for the development of molecular electronics devices and as thermochromic compounds.

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