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Carl-Georg Freiherr von Richthofen, Anja Stammler, Hartmut Bögge and Thorsten Glaser Synthesis and Characterization of Trinuclear NiII3 and CuII3 Triplesalophen Complexes: Evaluation of Ligand Folding and Heteroradialene Formation and their Impact on the Magnetic Properties European Journal of Inorganic Chemistry 2012

Version of Record online: 7 NOV 2012 | DOI: 10.1002/ejic.201200990

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The trinuclear NiII3 and CuII3 triplesalophen complexes exhibit planar molecular structures by the completely sp2 hybridized backbone leading to intermolecular π stacking. The CuII3 complexes exhibit ferromagnetic interactions although a strong heteroradialene contribution is observed.

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