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Thirumanavelan Gandhi, Subramani Rajkumar, V. Prathyusha and U. Deva Priyakumar Synthesis and Reactivity Studies of Dicationic Dihydrogen Complexes Bearing Sulfur-Donor Ligands: A Combined Experimental and Computational Study European Journal of Inorganic Chemistry 2013

Version of Record online: 1 FEB 2013 | DOI: 10.1002/ejic.201201022

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A series of dihydrogen complexes trans-[Ru(η2-H2){SC(SR)H}(dppe)2][X][BF4] (R = CH3, X = OTf; R = C6H5CH2, X = BPh4; R = H2C=CHCH2, X = BPh4; dppe = Ph2PCH2CH2PPh2) bearing sulfur-donor ligands has been synthesized by protonation of the (alkyl dithioformate)hydrido complexes trans-[Ru(H){SC(SR)H}(dppe)2][X] by using HBF4·Et2O.

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