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Sonia Pérez-Yáñez, Garikoitz Beobide, Oscar Castillo, Michael Fischer, Frank Hoffmann, Michael Fröba, Javier Cepeda and Antonio Luque Gas Adsorption Properties and Selectivity in CuII/Adeninato/Carboxylato Metal–Biomolecule Frameworks European Journal of Inorganic Chemistry 2012

Version of Record online: 19 NOV 2012 | DOI: 10.1002/ejic.201201028

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The gas adsorption capacity of CuII/adeninato/carboxylato MBioFs was analyzed on the basis of experimental and simulation data. The selectivity towards CO2/H2 and CO/H2 gas mixtures was studied by computing the Henry constants and the binary adsorption isotherms. The results show how the sorption features are controlled by modifying the chain length of the carboxylato ligand.

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