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B. Kishore Babu, A. R. Biju, Sailaja Sunkari, M. V. Rajasekharan and J. -P. Tuchagues Tetranuclear Copper Azido Complex of 4,5-Diazafluoren-9-one European Journal of Inorganic Chemistry 2013

Article first published online: 23 JAN 2013 | DOI: 10.1002/ejic.201201057

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The propensity of 4,5-diazafluoren-9-one to chelate through one short and one long bond allows the formation of an azide-bridged tetranuclear CuII complex, which crystallises as a molecular mixture of two distortion isomers of the open bicubane type. Ferromagnetic interactions dominate in both isomers.

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