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Ryo Ishimoto, Keigo Kamata and Noritaka Mizuno Investigation of the Reaction Mechanism for the Epoxidation of Alkenes with Hydrogen Peroxide Catalyzed by a Protonated Tetranuclear Peroxotungstate with NMR Spectroscopy, Kinetics, and DFT Calculations European Journal of Inorganic Chemistry 2013

Article first published online: 4 DEC 2012 | DOI: 10.1002/ejic.201201058

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A tetranuclear peroxotungstate [H{W2O2(O2)4(μ-O)}2]3– (I) showed high catalytic activity for epoxidation with H2O2. On the basis of the kinetic, mechanistic, spectroscopic, and theoretical investigations, it was found that I is the active species and that oxygen transfer from I to a C=C double bond is the rate-determining step.

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