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Antoine Tissot, Helena J. Shepherd, Loic Toupet, Eric Collet, Joelle Sainton, Gabor Molnár, Philippe Guionneau and Marie-Laure Boillot Temperature- and Pressure-Induced Switching of the Molecular Spin State of an Orthorhombic Iron(III) Spin-Crossover Salt European Journal of Inorganic Chemistry 2013

Article first published online: 19 DEC 2012 | DOI: 10.1002/ejic.201201059

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The spin-state switching of [(TPA)Fe(TCC)]SbF6 [TPA = tris(2-pyridylmethyl)amine, TCC2– = 3,4,5,6-tetrachlorocatecholate dianion] is investigated under stimulation by temperature or pressure. Both processes follow the same structural mechanism and are compared to those observed for the PF6 salt.

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