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Sophie Ehle, Volker Brüser, Volker Lorenz, Cristian G. Hrib, Katja Saulich, Siegfried Müller, Antje Quade and Frank T. Edelmann Linear Heterometallic Co3Li2 and Co4Li2 Siloxides: Precursors for the Plasma Synthesis of Adsorbent Materials European Journal of Inorganic Chemistry 2013

Version of Record online: 3 JAN 2013 | DOI: 10.1002/ejic.201201060

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Linear heterometallic Co3Li2 and Co4Li2 arrays, (thf)Co[Co{μ-(Ph2SiO)2O}{(μ-Cl)2Li(thf)2}]2 (5) and [Co2(μ-Cy7Si7O12)(μ-OSiMe3)(μ-Cl){Li(thf)2}2]2 (6), were prepared and characterized. Plasma treatment of 5 was found to activate the surface by creating –C–O, –C=O, and –COO functionalities. An initial study revealed promising formaldehyde adsorption properties for the plasma-treated material 5a.

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