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Danny Müller, Christian Knoll, Berthold Stöger, Werner Artner, Michael Reissner and Peter Weinberger A Modified Synthetic Pathway for the Synthesis of so far Inaccessible N1-Functionalized Tetrazole Ligands – Synthesis and Characterization of the 1D Chain-Type Spin Crossover Compound [Fe(3ditz)3](BF4)2 European Journal of Inorganic Chemistry 2013

Article first published online: 17 JAN 2013 | DOI: 10.1002/ejic.201201062

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A “new” synthetic “pathway“ allows the preparation of tetrazole ligands that were so far not accessible. The synthesis and characterization of new spin-crossover compound [Fe(3ditz)3](BF4)2 is described. Despite of the flexibility of the 1,3-bis(tetrazol-1-yl)propane (3ditz) ligand, a perfect packing of the coordination polymer enhances the cooperativity of the spin transition at Tequation image = 159 K.

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