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Nicolas Paradis, Guillaume Chastanet, François Varret and Jean-François Létard Metal Dilution of Cooperative Spin-Crossover Compounds: When Stable and Metastable High-Spin States Meet European Journal of Inorganic Chemistry 2013

Version of Record online: 2 JAN 2013 | DOI: 10.1002/ejic.201201084

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The photomagnetic properties of metal-diluted spin-crossover complexes [FexMn1–x(bpp)2](BF4)2 [bpp = 2,6-bis(pyrazol-3-yl)pyridine] have been investigated. The consequences of the overlap between the stable high-spin state at high temperature and the metastable high-spin state generated by light irradiation (or by thermal trapping) are discussed.

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