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Nanthawat Wannarit, Olivier Roubeau, Sujittra Youngme and Patrick Gamez Subtlety of the Spin-Crossover Phenomenon Observed with Dipyridylamino-Substituted Triazine Ligands European Journal of Inorganic Chemistry 2013

Version of Record online: 27 NOV 2012 | DOI: 10.1002/ejic.201201085

Thumbnail image of graphical abstract

Reaction of 4,6-dichloro-N,N-di(pyridine-2-yl)-1,3,5-triazine-amine (Cldpat; R = Cl) with Fe(NCS)2 yields a high-spin complex while 6-chloro-N′-phenyl-N,N-di(pyridin-2-yl)-1,3,5-triazine-2,4-diamine (Cladpat; R = aniline) generates a SCO compound.

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