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Dongdi Zhang, Yanhui Zhang, Juan Zhao, Pengtao Ma, Jingping Wang and Jingyang Niu Four Members of the Sandwich-Type Polytungstophosphate Family Based on Pentalacunary [HPW7O28]8– Building Blocks European Journal of Inorganic Chemistry 2013

Article first published online: 6 DEC 2012 | DOI: 10.1002/ejic.201201089

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Four new sandwich complexes were formed in which two [HPW7O28]8– lacunary Keggin clusters encapsulate a single transitional ion to give clusters with the general formula [MII(HPW7O28)2]14– (in which M = Co, Cd, and Mn). [FeIII(HPW7O28)2]13– was found to display moderately good electrocatalytic activity towards the reduction of nitrite.

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