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Rufeida Mohammed, Guillaume Chastanet, Floriana Tuna, Tamsin L. Malkin, Simon A. Barrett, Colin A. Kilner, Jean-François Létard and Malcolm A. Halcrow Synthesis of 2,6-Di(pyrazol-1-yl)pyrazine Derivatives and the Spin-State Behavior of Their Iron(II) Complexes European Journal of Inorganic Chemistry 2013

Version of Record online: 4 DEC 2012 | DOI: 10.1002/ejic.201201100

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Seven 2,6-di(pyrazol-1-yl)pyrazines substituted at the pyrazole 4-positions, and some of their iron complexes, are presented. The solid-state complexes exhibit various spin-state behaviors, including high spin, temperature-invariant mixed spin, thermal spin-crossover, and the LIESST effect. In solution, the pyrazinyl ligands slightly stabilize the low-spin states of the compounds.

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