Agata Białońska, Robert Bronisz and Łukasz Baranowski 1D Spin-Crossover Networks Containing a FeII(1,2,3-triazol-1-yl)4(CH3CN)2-Type Core European Journal of Inorganic Chemistry 2013
Bis(1,2,3-triazol-1-yl)methane (mbtr) was used to prepare 1D networks in which neighboring iron(II) ions are tethered by two semiflexible ligand molecules. The new Fe(1,2,3-triazolyl)4(CH3CN)2-type core based complexes exhibit thermally induced spin crossover. The ligand possesses the shortest possible alkyl spacer and shows remarkable elasticity triggered by a high spin [lrarr2] low spin transition.
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