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Xin Zhang, Shu-Xia Liu, Shu-Jun Li, Yu-Huan Gao, Xue-Na Wang, Qun Tang and Yi-Wei Liu Two Members of the {X4Nb16O56} Family (X = Ge, Si) Based on [(GeOH)2Ge2Nb16H2O54]12– and [K(GeOH)2Ge2Nb16H3O54]10– European Journal of Inorganic Chemistry 2013

Version of Record online: 28 FEB 2013 | DOI: 10.1002/ejic.201201117

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Two new GeIV-containing heteropolyniobates are constructed by a hydrothermal–conventional combination approach. Compound 1 is an isolated cluster and compound 2 exhibits the first 1D ladder-like Ge/Nb heteropolyniobate cluster with μ-K atoms bridging them into extended structures. The photoluminescence and electrochemical properties of both compounds are investigated.

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