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Olivier Roubeau, Patrick Gamez and Simon J. Teat Dinuclear Complexes with a Triple N1,N2-Triazole Bridge That Exhibit Partial Spin Crossover and Weak Antiferromagnetic Interactions European Journal of Inorganic Chemistry 2013

Article first published online: 26 NOV 2012 | DOI: 10.1002/ejic.201201126

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Two new structurally characterized coordination compounds with a sole triple N1,N2-1,2,4-triazole bridge are reported with 4-phenylimino-1,2,4-triazole as ligand. The structural parameters of this unique coordination link are reviewed and analyzed. The FeII analogue exhibits gradual incomplete spin crossover centred at 115 K.

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