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Hongjin Lv, Jie Song, Yurii V. Geletii, Weiwei Guo, John Bacsa and Craig L. Hill A Hexanuclear Cobalt(II) Cluster Incorporated in a Banana-Shaped Tungstovanadate: [(Co(OH2)Co2VW9O34)2(VW6O26)]17– European Journal of Inorganic Chemistry 2013

Article first published online: 19 DEC 2012 | DOI: 10.1002/ejic.201201130

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The hexacobalt tungstovanadate, Na17[(Co(OH2)Co2VW9O34)2(VW6O26)]·31H2O (1), has been prepared and characterized both in the solid state and in solution. It crystallizes in the monoclinic space group P21/c, and consists of two tri-CoII substituted B-α-[(Co(OH2)Co2VW9O39)] Keggin units bridged by one unique [VW6O16] fragment, leading to a banana-shaped structure with idealized C2ν symmetry.

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