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Jordi Rich, Montserrat Rodríguez, Isabel Romero, Xavier Fontrodona, Piet W. N. M. van Leeuwen, Zoraida Freixa, Xavier Sala, Albert Poater and Miquel Solà N-Tetradentate SPANamine Derivatives and Their MnII-Complexes as Catalysts for Epoxidation of Alkenes European Journal of Inorganic Chemistry 2013

Article first published online: 20 DEC 2012 | DOI: 10.1002/ejic.201201154

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A new family of tetradentate N-donor spiro ligands and the corresponding mononuclear manganese(II) complexes have been fully characterized. Their catalytic ability in styrene epoxidation in the presence and absence of additives is also described. The stereospecificity of one of the catalysts in the epoxidation of cis-β-methylstyrene has been corroborated by computational calculations.

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