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Di Gao, Gabriel Canard, Michel Giorgi and Teodor Silviu Balaban Synthesis and Characterization of Copper Undecaarylcorroles and the First Undecaarylcorrole Free Base European Journal of Inorganic Chemistry 2012

Version of Record online: 20 NOV 2012 | DOI: 10.1002/ejic.201201158

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Saddle undecaaryl copper corroles were prepared by a Suzuki cross-coupling procedure. Their saddling dihedral angles strongly depend on the meso substituents, whereas the β-aryl groups induce a redshift of their UV/Vis absorption maxima. The X-ray structure of the demetalated undecaarylcorrole free base shows that full aryl substitution has no impact on the conformation of the corrole.

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