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Alan R. Crozier, Karl W. Törnroos, Cäcilia Maichle-Mössmer and Reiner Anwander Trivalent Cerium and Praseodymium Aromatic Ketone Adducts European Journal of Inorganic Chemistry 2013

Version of Record online: 26 NOV 2012 | DOI: 10.1002/ejic.201201171

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Trivalent homoleptic hexamethylsilylamido and cyclopentadienyl complexes of cerium and praseodymium, Ln[N(SiMe3)2]3 and Ln(C5H5)3, readily form monoadducts with benzophenone or 9-fluorenone, which display significant ligand-to-metal charge transfer.

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