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Sebastian Schlecht, Maik Finze, Rüdiger Bertermann, Walter Frank, Anke Domann and Manfred Braun Cocrystallising Rotamers of a Pentacoordinate Silicon Complex with a Chiral Aminodiol Ligand European Journal of Inorganic Chemistry 2013

Article first published online: 25 JAN 2013 | DOI: 10.1002/ejic.201201173

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The interconversion of turnstile rotamers at silicon, readily occurring in solution, is frozen in the solid state. Therein, the pentacoordinate complexes featuring a homochiral backbone are reported as the first examples of cocrystallising rotamers at silicon.

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