Montserrat Barquín, Roberto Ciganda, María A. Garralda, Lourdes Ibarlucea, Claudio Mendicute-Fierro, Antonio Rodríguez-Diéguez and José M. Seco Iridium and Rhodium Complexes with the Hemilabile Ligand [2-(1,3-Dioxolane-2-yl)phenyl]diphenylphosphane – Behaviour in Solution and Structural Characterization European Journal of Inorganic Chemistry 2013
[2-(1,3-Dioxolane-2-yl)phenyl]diphenylphosphane (1) coordinates to MI preferably as a κ1-P ligand. MIII may afford κ2-P,O coordination in dynamic diastereomers such as A or B. A contains a single diastereomer if M = Ir or two diastereomers in a 95:5 ratio if M = Rh. B contains a mixture of only two diastereomers.
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