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Johannes Obenauf, Winfried P. Kretschmer, Tobias Bauer and Rhett Kempe An Efficient Titanium Amidinate Catalyzed Version of Ziegler's “Aufbaureaktion” European Journal of Inorganic Chemistry 2013

Version of Record online: 7 DEC 2012 | DOI: 10.1002/ejic.201201194

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New ammonium titanates undergo polyethylenyl chain transfer polymerization to triethylaluminium after activation with d-MAO (“dry methylaluminoxane”). Polymerization activities of up to 1000 kgPE molcat–1 h–1 bar–1 in the presence of 1000 equiv. of triethylaluminium were observed. Linear aluminium-terminated polyethylene is found. This polymerization process can be viewed as an efficient version of Ziegler's “Aufbaureaktion”.

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