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Santiago Reinoso, Pablo Vitoria, Leire San Felices and Juan M. Gutiérrez-Zorrilla Diiron(III)-Containing 23-Tungsto-2-Borate: First Evidence of 3d Metal Substitution in the {BW13} Framework European Journal of Inorganic Chemistry 2013

Version of Record online: 20 DEC 2012 | DOI: 10.1002/ejic.201201196

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[{FeIII(H2O)3}2(WO2)(HBW11O39)2]8–, the first 3d-metal-containing tungstoborate whose structure differs from that of a monosubstituted Keggin framework, illustrates the possibility of performing substitutions of tungsten by 3d metals in the capping positions of the 13-tungstoborate skeleton.

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