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Sara Dolci, Fabio Marchetti, Guido Pampaloni and Stefano Zacchini The Reactivity of Molybdenum Pentachloride with Ester Molecules: Ester Activation, Metal Reduction, and Synthesis of 1D Coordination Polymers European Journal of Inorganic Chemistry 2013

Version of Record online: 8 JAN 2013 | DOI: 10.1002/ejic.201201217

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The reactions of esters with molybdenum pentachloride in noncoordinating solvents proceed selectively with either activation of the organic reactant or metal reduction. Two crystallographically characterized MoCl4-based 1D coordination polymers are reported.

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