Shiwen Li, Rongji Liu, Rosa Ngo Biboum, Bénédicte Lepoittevin, Guangjin Zhang, Anne Dolbecq, Pierre Mialane and Bineta Keita First Examples of Hybrids Based on Graphene and a Ring-Shaped Macrocyclic Polyoxometalate: Synthesis, Characterization, and Properties European Journal of Inorganic Chemistry 2013
We report the facile synthesis of the first hybrids based on graphene (G) and the macrocyclic polyoxometalate [H7P8W48O184]33– (P8W48) alone or assembled with a PIL. Both methods lead to the production of stable water-dispersible P8W48@G hybrids. The hybrids were fully characterized by various spectroscopic methods, microscopy, and electrochemistry.
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