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Oksana Toma, Nicolas Mercier and Chiara Botta N-Methyl-4,4′-bipyridinium and N-Methyl-N′-oxide-4,4′-bipyridinium Bismuth Complexes – Photochromism and Photoluminescence in the Solid State European Journal of Inorganic Chemistry 2013

Article first published online: 10 JAN 2013 | DOI: 10.1002/ejic.201201233

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Three bismuth complexes based on N-methyl-4,4′-bipyridinium (hMV+), (hMV)[Bi(hMV)Cl5] (1), and N-methyl-N′-oxide-4,4′-bipyridinium (MVO+), [Bi(MVO)X4(dmso)]·dmso [X = Cl (2), Br (3)], show strong photoluminescence in the solid state. Upon UV irradiation, 1 undergoes a photoinduced charge-transfer (PICT) process resulting in a color change from white to blue.

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