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Sudesh T. Manjare, Harkesh B. Singh and Ray J. Butcher Oxidation of Carbene-Derived Selenium Diiodide with Silver Tetrafluoroborate – Isolation of Iodonium Ion Complexes with Selones European Journal of Inorganic Chemistry 2013

Version of Record online: 20 FEB 2013 | DOI: 10.1002/ejic.201201238

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The reactions of diiodoselones with silver tetrafluoroborate result in the formation of N-heterocyclic carbene (NHC) derived selone coordinated iodonium ions with BF4/BF4·I3 as counteranions. The diiodoselones are intermediates in the formation of iodonium ion complexes. The complexes exhibit interesting supramolecular assemblies.

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