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Richard Villanneau, Aïcha Ben Djamâa, Lise-Marie Chamoreau, Geoffrey Gontard and Anna Proust Bisorganophosphonyl and -Organoarsenyl Derivatives of Heteropolytungstates as Hard Ligands for Early-Transition-Metal and Lanthanide Cations European Journal of Inorganic Chemistry 2013

Version of Record online: 4 JAN 2013 | DOI: 10.1002/ejic.201201257

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The coordination properties of polyoxometalate (POM) hybrids that incorporate organophosphonyl or -arsenyl functions were studied toward cations from different families of the periodic table (La3+, Ca2+, V5+, Ti4+). The structures of all complexes were determined by single-crystal X-ray diffraction and showed evidence for the particular hardness of the coordination sites in these POM hybrids.

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