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Xiaoyu Liu, Li Wang, Xuena Yin and Rudan Huang Assembly of Hybrid Materials Based on a Lanthanide–Organic Framework and a Keggin-Type [PMo12–xVxO40](3+x)– (x = 1, 2) Cluster European Journal of Inorganic Chemistry 2013

Version of Record online: 6 FEB 2013 | DOI: 10.1002/ejic.201201275

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A series of polyoxometalate-based hybrid compounds, [Ln4(pdc)4(H2O)16][PMo11VO40]·2H2O (15) and [Ln4(pdc)4(H2O)16][HPMo10V2O40]·H2O (6, 7) (Ln = La, Ce, Pr, Nd, Sm for 15 and Ln = La and Ce for 6 and 7; H2pdc = pyridine-2,6-dicarboxylic acid), were synthesized and characterized. Moreover, photoluminescent properties, electrochemical properties, and catalytic properties were investigated.

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