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Aurore Thibon, Lydia Karmazin-Brelot and Dominique Mandon Coordination Versatility and Amide Shift in Mononuclear FeII Complexes with the Asymmetrical Tripod [(6-Bromo-2-pyridyl)methyl][(6-pivaloylamido-2-pyridyl)methyl](2-pyridylmethyl)amine (BrMPPA) European Journal of Inorganic Chemistry 2013

Article first published online: 11 JAN 2013 | DOI: 10.1002/ejic.201201284

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In the new BrMPPA tripod, di-α-substitution by an amido group and a bromine atom, respectively, provide functionality and sterically induced ligand flexibility in FeII complexes. Three different coordination modes of the tripod are described, the occurrence of which depends on the nature of the ancillary ligands.

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