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Yusuke Matsuki, Yuki Mouri, Yoshitaka Sakai, Satoshi Matsunaga and Kenji Nomiya Monomer and Dimer of Mono-titanium(IV)-Containing α-Keggin Polyoxometalates: Synthesis, Molecular Structures, and pH-Dependent Monomer–Dimer Interconversion in Solution European Journal of Inorganic Chemistry 2013

Version of Record online: 23 JAN 2013 | DOI: 10.1002/ejic.201201290

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The monomer (Et2NH2)5[α-PW11TiO40]·2H2O and μ-oxo dimer (Et2NH2)8[(α-PW11TiO39)2O]·6H2O of mono-titanium(IV)-containing α-Keggin polyoxometalates (POMs) were successfully prepared. The molecular structure of the dimeric polyoxoanion with a μ-oxo group in 2 has been determined for the first time. The monomer–dimer equilibrium in solution was clarified by pH-varied 31P NMR spectroscopy.

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