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Damien Prieur, Ursula Carvajal-Nunez, Tonya Vitova and Joseph Somers Local and Electronic Structure of Americium-Bearing PuO2 European Journal of Inorganic Chemistry 2013

Article first published online: 28 JAN 2013 | DOI: 10.1002/ejic.201201294

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Coupling XRD and X-ray absorption spectroscopy techniques have shown that a biphasic fluorite Am-bearing PuO2 material is obtained following sintering in moisturized Ar/H2. Heating of this sample in air ensured the formation of a substoichiometric fluorte Pu+IV0.80Am+III/+IV0.20O1.98 solid solution.

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