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Qingfu Zhang, Hongguo Hao, Haina Zhang, Suna Wang, Juan Jin and Dezhi Sun Two Enantiomorphic MgII/Carboxylate Coordination Polymers Produced from Spontaneous Resolution with an Achiral Bipyridyl Dicarboxylate Ligand European Journal of Inorganic Chemistry 2013

Article first published online: 15 JAN 2013 | DOI: 10.1002/ejic.201201359

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Two enantiomorphic MgII/carboxylate coordination polymers [Mg(bpda)(H2O)4]n (1M and 1P) have been obtained by spontaneous resolution from achiral precursors, 2,2′-bipyridyl-3,3′-dicarboxylic acid (H2bpda) and Mg(NO3)2·6H2O, upon crystallization without any chiral auxiliary.

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