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Ivan V. Ananyev, Sergey E. Nefedov and Konstantin A. Lyssenko From Coordination Polyhedra to Molecular Environment and Back – Interplay between Coordinate and Hydrogen Bonds in Two Polymorphs of a Cobalt Complex European Journal of Inorganic Chemistry 2013

Version of Record online: 4 APR 2013 | DOI: 10.1002/ejic.201201363

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A thorough analysis of the chemical bonding patterns in two polymorphs of a cobalt(II) benzoate complex with substituted pyrazole ligands by using Bader's “Atoms in Molecules” theory reveals the crucial role of N–H···O hydrogen bonds in the stabilization of unfavorable [4+1] cobalt polyhedron.

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