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Takuya Shiga, Emiko Oshiro, Naoko Nakayama, Kiyotaka Mitsumoto, Graham N. Newton, Hiroyuki Nishikawa and Hiroki Oshio Dimerized Spin-Crossover Iron(II) Complexes as Supramolecular Anion Capsules European Journal of Inorganic Chemistry 2013

Article first published online: 16 JAN 2013 | DOI: 10.1002/ejic.201201365

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Two iron(II) complexes were synthesized using bulky capping ligands. They formed a dimerized capsulelike superstructure within which a hexafluorophosphate anion was encapsulated. The complexes were investigated by cryomagnetic studies, X-ray structural analyses, and Mössbauer spectra.

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