Takuya Shiga, Emiko Oshiro, Naoko Nakayama, Kiyotaka Mitsumoto, Graham N. Newton, Hiroyuki Nishikawa and Hiroki Oshio Dimerized Spin-Crossover Iron(II) Complexes as Supramolecular Anion Capsules European Journal of Inorganic Chemistry 2013
Two iron(II) complexes were synthesized using bulky capping ligands. They formed a dimerized capsulelike superstructure within which a hexafluorophosphate anion was encapsulated. The complexes were investigated by cryomagnetic studies, X-ray structural analyses, and Mössbauer spectra.
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